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Structures and labels in chemicals used to synthesize the protic ionic liquids: (A) monoethanolamine, MEA (M); (B) diethanolamine, DEA (D); (C) acetic acid (A); and (D) <t>hexanoic</t> <t>acid</t> (H).
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Structures and labels in chemicals used to synthesize the protic ionic liquids: (A) monoethanolamine, MEA (M); (B) diethanolamine, DEA (D); (C) acetic acid (A); and (D) hexanoic acid (H).

Journal: The Journal of Physical Chemistry. B

Article Title: Protic Ionic Liquid–H 2 O MixturesStructure, Interactions, and Structure–Property Relationships

doi: 10.1021/acs.jpcb.5c07863

Figure Lengend Snippet: Structures and labels in chemicals used to synthesize the protic ionic liquids: (A) monoethanolamine, MEA (M); (B) diethanolamine, DEA (D); (C) acetic acid (A); and (D) hexanoic acid (H).

Article Snippet: Four protic ionic liquids (PILs) were synthesized using the following chemicals without further purification: monoethanolamine (purity >99 wt %, Fisher Scientific, CAS no. 141-43-5), diethanolamine (99 wt %, ThermoFisher, CAS no. 111-42-2), acetic acid (99 wt %, Fisher Scientific, CAS no. 64-19-7), hexanoic acid (99 wt %, ThermoFisher, CAS no. 142-62-1), methanol (>99 wt %, Honeywell), and deuterium oxide (isotopic purity >99.99%, Sigma-Aldrich).

Techniques:

Visualization of the main trends determined in this study. Carbon atoms in the cation and anion substrates are presented with different colors (pink: monoethanolamine, MEA (M); yellow: diethanolamine, DEA (D); rose pink: acetic acid (A); and blue: hexanoic acid (H)). The color codes of oxygen (red), nitrogen (navy), and hydrogen (white) are consistent for all molecules.

Journal: The Journal of Physical Chemistry. B

Article Title: Protic Ionic Liquid–H 2 O MixturesStructure, Interactions, and Structure–Property Relationships

doi: 10.1021/acs.jpcb.5c07863

Figure Lengend Snippet: Visualization of the main trends determined in this study. Carbon atoms in the cation and anion substrates are presented with different colors (pink: monoethanolamine, MEA (M); yellow: diethanolamine, DEA (D); rose pink: acetic acid (A); and blue: hexanoic acid (H)). The color codes of oxygen (red), nitrogen (navy), and hydrogen (white) are consistent for all molecules.

Article Snippet: Four protic ionic liquids (PILs) were synthesized using the following chemicals without further purification: monoethanolamine (purity >99 wt %, Fisher Scientific, CAS no. 141-43-5), diethanolamine (99 wt %, ThermoFisher, CAS no. 111-42-2), acetic acid (99 wt %, Fisher Scientific, CAS no. 64-19-7), hexanoic acid (99 wt %, ThermoFisher, CAS no. 142-62-1), methanol (>99 wt %, Honeywell), and deuterium oxide (isotopic purity >99.99%, Sigma-Aldrich).

Techniques: